GLYCIDYL PHENYL ETHER
Phenyl Glycidyl Ether
CAS: 122-60-1
Molecular Formula: C9H10O2
GLYCIDYL PHENYL ETHER - Names and Identifiers
| Name | Phenyl Glycidyl Ether |
| Synonyms | PGE PHENYL GLYCID ETHER PHENYL GLYCIDYL ETHER Phenyl tlycidyl ether Glycidyl Phenyl Ether Phenyl Glycidyl Ether GLYCIDYL PHENYL ETHER 3-phenoxy-1,2-epoxypropane 2,3-EPOXYPROPYL PHENYL ETHER PHENYL 2,3-EPOXYPROPYL ETHER 1-PHENOXY-2,3-PROPYLENE OXIDE |
| CAS | 122-60-1 |
| EINECS | 204-557-2 |
| InChI | InChI=1/C6H10O3.C6H6O/c1(5-3-8-5)7-2-6-4-9-6;7-6-4-2-1-3-5-6/h5-6H,1-4H2;1-5,7H |
| InChIKey | FQYUMYWMJTYZTK-UHFFFAOYSA-N |
GLYCIDYL PHENYL ETHER - Physico-chemical Properties
| Molecular Formula | C9H10O2 |
| Molar Mass | 150.17 |
| Density | 1.109g/mLat 25°C(lit.) |
| Melting Point | 3.5°C(lit.) |
| Boling Point | 245-247°C(lit.) |
| Flash Point | >230°F |
| Water Solubility | 2.4 g/L (20 ºC) |
| Solubility | 2.4g/l |
| Vapor Presure | 0.03 mm Hg ( 20 °C) |
| Vapor Density | 5.2 (vs air) |
| Appearance | Liquid |
| Color | Clear colorless to yellow |
| Exposure Limit | TLV-TWA 6 mg/m3(1 ppm) (ACGIH);1 ppm (15 min) (NIOSH). |
| BRN | 2744 |
| Storage Condition | Store below +30°C. |
| Stability | Stable. Incompatible with strong oxidizing agents. |
| Refractive Index | n20/D 1.531 |
| Physical and Chemical Properties | Colorless transparent liquid. Melting point 3.5 ℃, boiling point 242.5 ℃(100kPa), relative density 1.1109(21.2/4 ℃), refractive index 1.5307(21 ℃). Soluble in ether, benzene, insoluble in water, with water vapor volatilization. |
GLYCIDYL PHENYL ETHER - Risk and Safety
| Hazard Symbols | T - Toxic |
| Risk Codes | R45 - May cause cancer R20 - Harmful by inhalation R37/38 - Irritating to respiratory system and skin. R43 - May cause sensitization by skin contact R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R68 - Possible risk of irreversible effects |
| Safety Description | S53 - Avoid exposure - obtain special instructions before use. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) S61 - Avoid release to the environment. Refer to special instructions / safety data sheets. |
| UN IDs | 2810 |
| WGK Germany | 3 |
| RTECS | TZ3675000 |
| TSCA | Yes |
| HS Code | 29109000 |
| Hazard Class | IRRITANT |
| Toxicity | LD50 orally in Rabbit: 2150 mg/kg LD50 dermal Rabbit 1500 mg/kg |
GLYCIDYL PHENYL ETHER - Reference Information
| LogP | 1.61 at 25℃ |
| (IARC) carcinogen classification | 2B (Vol. 47, 71) 1999 |
| NIST chemical information | information provided by: webbook.nist.gov (external link) |
| EPA chemical substance information | information provided by: ofmpeb.epa.gov (external link) |
| Use | is useful as an intermediate in organic synthesis. |
| production method | is obtained by condensation of phenol and epichlorohydrin in the presence of sodium hydroxide. Phenol and sodium hydroxide were mixed and stirred until all were dissolved, cooled to 5-6 °c, and epichlorohydrin was slowly added. After the addition, the mixture was stirred at 25 ° C. For 45H. The reaction was extracted with ether, and the extract was dried with anhydrous potassium carbonate and filtered. The diethyl ether was recovered from the filtrate and distilled under reduced pressure to obtain an epoxy propyl phenyl ether fraction at a temperature of 1.46-123 °c (kPa). |
| category | toxic substances |
| toxicity grade | poisoning |
| Acute toxicity | oral-rat LD50: 3850 mg/kg; Oral-mouse LD50: 1400 mg/kg |
| stimulation data | Skin-rabbits 10 mg/24 h severe; eye-rabbit 111 mg mild |
| explosive hazard characteristics | can form peroxide; The latter can be exploded |
| flammability hazard characteristics | open flame flammability; Toxic vapor release when exposed to heat |
| storage and transportation characteristics | The warehouse is ventilated and dried at low temperature; Separate from food and oxidant |
| fire extinguishing agent | foam, dry powder, carbon dioxide, water mist |
| Occupational Standard | TWA 6 mg/m3; Tel 60 mg/m3 |
| spontaneous combustion temperature | 430°C |
| toxic substance data | information provided by: pubchem.ncbi.nlm.nih.gov (external link) |
| immediate life-and health-threatening concentration | 100 ppm |
Last Update：2024-04-09 02:00:04
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View History
GLYCIDYL PHENYL ETHER
乳化剂OS
RARECHEM AL BW 2147
NSC 75799
Thorium
FLUORINERT FC-77
FEMA 2044
O-XYLENE BIS(TRIPHENYLPHOSPONIUM BROMIDE)
3-(4-Chlorophenoxy)piperidine
Benzyl acid
乳化剂OS
RARECHEM AL BW 2147
NSC 75799
Thorium
FLUORINERT FC-77
FEMA 2044
O-XYLENE BIS(TRIPHENYLPHOSPONIUM BROMIDE)
3-(4-Chlorophenoxy)piperidine
Benzyl acid